Influence of TiO2 Morphology and Crystallinity on Visible-Light Photocatalytic Activity of TiO2-Bi2O3 Composite in AOPs

Abstract

Solution combustion synthesis was used to produce a junction between different TiO2 supports (anatase TiO2 nanorods (TNR) and nanoparticles (TNP) and TiO2 with anatase core and amorphous shell (a-TNR)) and narrow bandgap (BG) semiconductor β-Bi2O3. β-Bi2O3 acted as a visible-light photosensitizer and enabled us to carry out photocatalytic oxidation of water dissolved bisphenol A (BPA) with TiO2 based catalysts under visible-light illumination. Heterojunction between TiO2 and β-Bi2O3 in TNR + Bi and TNP + Bi composites enables the transfer of visible-light generated holes from the β-Bi2O3 valence band (VB) to the upper lying TiO2 VB. A p–n junction, established upon close chemical contact between TiO2 and β-Bi2O3, enables the transfer of visible-light generated electrons in the β-Bi2O3 conduction band (CB) to the TiO2 CB. In TNR + Bi and a-TNR + Bi composites, the supplied heat energy during the synthesis of samples was not sufficient to completely transform (BiO)2CO3 into β-Bi2O3. A p–n junction between (BiO)2CO3 and β-Bi2O3 enables the transfer of electrons generated by β-Bi2O3 to (BiO)2CO3. Hindered charge carrier recombination originating from the crystallinity of TiO2 is a more important factor in the overall kinetics of BPA degradation than high specific surface area of the amorphous TiO2 and reduction/oxidation of surface adsorbed substrates.