Abstract
Recently, an increasing number of metal complex catalysts have been developed to achieve the activation or transformation of substrates based on cooperation between the metal atom and its ligands. In such “cooperative catalysis,” the ligand not only is bound to the metal, where it exerts steric and electronic effects, but also functionally varies its structure during the elementary processes of the catalytic reaction. In this review article, we focus on metal–ligand cooperation involving aromatization and dearomatization of the ligand, thus introducing the newest developments and examples of homogeneous catalytic reactions.
Subject
Physical and Theoretical Chemistry,Catalysis
Reference245 articles.
1. Transition Metal Reagents and Catalysts: Innovations in Organic Synthesis;Tsuji,2000
2. Transition Metals in the Synthesis of Complex Organic Molecules;Hegedus,1994
3. Cooperating Ligands, in Catalysis, in Cooperative Catalysis: Designing Efficient Catalysts for Synthesis;Trincado,2015
4. Cooperating Ligands in Catalysis
5. The Catalyst Precursor, Catalyst, and Intermediate in the RuII-Promoted Asymmetric Hydrogen Transfer between Alcohols and Ketones
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