Effect of Biogenic Silica Behavior in the Incorporation of Mesoporous Anatase TiO2 for Excellent Photocatalytic Mineralization of Sodium Diclofenac

Abstract

TiO2/SiO2 composites were synthesized via a simple sol gel method by surface reduction of Ti4+ ions to Ti3+ using titanium isopropoxide as a TiO2 precursor and rice husks (RHA) as a SiO2 source. The silica content and calcination temperature of the materials were evaluated. Thermal, crystallographic and physicochemical aspects suggest that biogenic silica (SiO2) can improve the thermal stability of the anatase phase of TiO2, when the SiO2 content reaches 20%. The N2 adsorption-desorption isotherms showed that the SiO2-modified samples have uniform pore diameters and a large specific surface area. The XPS analysis showed the surface reduction of Ti4+ ions to Ti3+ within the TiO2 network via oxygen vacancies after SiO2 introduction, which is beneficial for the photocatalytic reaction. Photocatalytic degradation of sodium diclofenac (SDFC) shows that TiO2/SiO2 composites have better activity compared to commercial P25. Mesoporous TiO2 composite modified with 20 wt% SiO2 showed better photocatalytic mineralization than P25 (83.7% after 2 h instead of 57.3% for P25). The excellent photocatalytic mineralization of the photocatalysts can be attributed to the high anatase crystallinity exhibited by XRD analysis, high specific surface area, surface hydroxyl groups, and the creation of oxygen vacancy, as well as the presence of Ti3+ ions.