Cu-Y2O3 Catalyst Derived from Cu2Y2O5 Perovskite for Water Gas Shift Reaction: The Effect of Reduction Temperature

Abstract

Cu2Y2O5 perovskite was reduced at different temperatures under H2 atmosphere to prepare two Cu-Y2O3 catalysts. The results of the activity test indicated that the Cu-Y2O3 catalyst after H2-reduction at 500 °C (RCYO-500) exhibited the best performance in the temperature range from 100 to 180 °C for water gas shift (WGS) reaction, with a CO conversion of 57.30% and H2 production of 30.67 μmol·gcat−1·min−1 at 160 °C and a gas hourly space velocity (GHSV) of 6000 mL·gcat−1·h−1. The catalyst reduced at 320 °C (RCYO-320) performed best at the temperature range from 180 to 250 °C, which achieved 86.44% CO conversion and 54.73 μmol·gcat−1·min−1 H2 production at 250 °C. Both of the Cu-Y2O3 catalysts had similar structures including Cu°, Cu+, oxygen vacancies (Vo) on the Cu°-Cu+ interface and Y2O3 support. RCYO-500, with a mainly exposed Cu° (100) facet, was active in the low-temperature WGS reaction, while the WGS activity of RCYO-320, which mainly exposed the Cu° (111) facet, was greatly enhanced above 180 °C. Different Cu° facets have different abilities to absorb H2O and then dissociate it to form hydroxyl groups, which is the main step affecting the catalytic rate of the WGS reaction.