Xylene and n-Hexane Adsorption Performance of a Waste Methanol-to-Propylene Catalyst under Acid-Base Treatment

Abstract

Spent methanol-to-propylene (MTP) catalysts have a large specific surface area and high porosity but are usually directly disposed of in landfills, and recycling is rare. In this study, spent MTP catalyst was moderately dealuminized with acids and etched with an alkali solvent to increase its specific surface area. A novel adsorbent was obtained. XRD, SEM, FT-IR, XRD, XRF, and MAS-NMR characterization shows that the adsorbent maintains a typical ZSM-5 zeolite structure, and the dealumination effect of H2C2O4 is better than that of HCl. HCl mainly removes the framework aluminum of the molecular sieve; H2C2O4 not only removes the framework aluminum but also dissolves some of the nonframework aluminum, which increases the BET-specific surface area and pore diameter. The spent catalyst maintains an irregular ellipsoidal shape. After alkali treatment, the surface of the spherical particles becomes rough. With increasing alkali concentration, the damage degree increases. After treatment with 4 mol/L H2C2O4 and 0.1 mol/L NaOH, the p-xylene and n-hexane adsorption capacities reach the maximum, with values of 141.04 mg/g and 106.87 mg/g, respectively, 20.7% and 16.2% greater than those before treatment. These findings indicate that modified spent MTP catalyst has the potential for application in the removal of VOCs from the air.