Loading Nano-CuO on TiO2 Nanomeshes towards Efficient Photodegradation of Methylene Blue

Abstract

In order to improve the photocatalytic activity of TiO2, we successfully loaded nano-CuO on the TiO2 nanomeshes as CuO-TiO2 nanocomposites through a facile electrodeposition method. The optimized calcined temperature after Cu electrodeposition is confirmed as 450 °C, which could furthest assist the crystallization of anatase TiO2 and guarantee the high photocatalytic activity of CuO-TiO2 nanocomposites. Comparing with pure TiO2 nanomeshes, CuO-TiO2 nanocomposites showed better degradability of methylene blue, and the degradation efficiency reached to 35% after 120 min irradiation. Additionally, CuO-TiO2 nanocomposites exhibit much stronger absorption intensity within the visible light scope, more than two times than that of pure TiO2 nanomeshes, which indicates that the loading of nano-CuO could promote photocatalytic efficiency by the strong visible light absorption. Additionally, CuO-TiO2 nanocomposites show faster photocurrent response and lower charge transfer resistance than that of pure TiO2 nanomeshes, which implies that the recombination rate of photogenerated electron-hole pairs was reduced after nano-CuO loading.