Architecture Evolution of Different Nanoparticles Types: Relationship between the Structure and Functional Properties of Catalysts for PEMFC

Abstract

This review considers the features of the catalysts with different nanoparticle structures architecture transformation under the various pre-treatment types. Based on the results of the publications analysis, it can be concluded that the chemical or electrochemical activation of bimetallic catalysts has a significant effect on their composition, microstructure, and catalytic activity in the oxygen reduction reaction. The stage of electrochemical activation is recommended for use as a mandatory catalyst pre-treatment to obtain highly active de-alloyed materials. The literature is studied, which covers possible variants of the structural modification under the influence of thermal treatment under different processing conditions. Additionally, based on the literature data analysis, recommendations are given for the thermal treatment of catalysts alloyed with various d-metals.