Two Processes of Anglesite Formation and a Model of Secondary Supergene Enrichment of Bi and Ag in Seafloor Hydrothermal Sulfide Deposits

Abstract

The in situ element concentrations and the sulfur (S), and lead (Pb) isotopic compositions in anglesite were investigated for samples from seafloor hydrothermal fields in the Okinawa Trough (OT), Western Pacific. The anglesite grains are of two kinds: (1) low Pb/high S primary hydrothermal anglesite (PHA), which is formed by mixing of fluid and seawater, and (2) high Pb/low S secondary supergene anglesite (SSA), which is the product of low-temperature (<100 °C) alteration of galena in the seawater environment. The Ag and Bi in the SSA go through a second enrichment process during the formation of high Pb/low S anglesite by galena alteration, indicating that the SSA and galena, which may be the major minerals host for considerable quantities of Ag and Bi, are potentially Ag-Bi-enriched in the back-arc hydrothermal field. Moreover, REEs, S and Pb in the OT anglesite are likely to have been leached by fluids from local sub-seafloor volcanic rocks and/or sediments. A knowledge of the anglesite is useful for understanding the influence of volcanic rocks, sediments and altered subducted oceanic plate in hydrothermal systems, showing how trace metals behave during the formation of secondary minerals.