Determination of Contaminant Transport Parameters for a Local Aquifer by Numerical Modeling of Two Plumes: Trichloroethylene and Hexavalent Chromium

Abstract

The municipal wellfield in Collierville, Tennessee, is contaminated with trichloroethylene (TCE) and hexavalent chromium (Cr (VI)) due to industrial operations dating back to the 1970s and 1980s. This study aims to elucidate the aquifer’s contaminant transport mechanisms by determining longitudinal and transverse dispersivities through inverse modeling. Utilizing MT3DMS for contaminant transport simulation, based on a well-calibrated groundwater flow model, and leveraging Python’s multiprocessing library for efficiency, the study employs a trial-and-error methodology. Key findings reveal that longitudinal dispersivity values range from 5.5 m near the source to 20.5 m further away, with horizontal and vertical transverse dispersivities between 0.28 m and 3.88 m and between 0.03 m and 0.08 m, respectively. These insights into the aquifer’s dispersivity coefficients, which reflect the scale-dependent nature of longitudinal dispersivity, are crucial for optimizing remediation strategies and achieving cleanup goals. This study underscores the importance of accurate parameter estimation in contaminant transport modeling and contributes to a better understanding of contaminant dynamics in the Collierville wellfield.