Thermal Diffusivity of Aqueous Dispersions of Silicon Oxide Nanoparticles by Dual-Beam Thermal Lens Spectrometry

Author:

Khabibullin Vladislav R.1ORCID,Usoltseva Liliya O.1ORCID,Mikheev Ivan V.1ORCID,Proskurnin Mikhail A.1ORCID

Affiliation:

1. Analytical Chemistry Division, Chemistry Department, M.V. Lomonosov Moscow State University, d. 1, Str. 3, Lenin Hills, GSP-1 V-234, Moscow 119991, Russia

Abstract

The growing interest in heat-conducting nanofluids requires highly sensitive methods for analyzing the thermal properties. Thermal lens spectrometry (TLS), despite its advantages over classical methods, does not have a general approach for measuring and interpreting results for dispersed systems. In this paper, for nanofluids of silicon oxide in water in a wide range of concentrations and sizes, the selection of measurement parameters for transient and steady-state thermal lensing is justified, and the interpretation of the results of thermal diffusivity measurements is substantiated. The features of the measurements of thermal diffusivity by TLS under stationary states for dispersed systems are considered. Using this approach, it is possible to detect and distinguish thermal effects with high accuracy. For dispersions of silicon oxide, with increasing concentrations, the thermal diffusivity passes through a minimum threshold. Silicon oxide dispersions can be used both as coolants or as heat-removing liquids by selecting the particle size and concentration.

Funder

RFBR

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

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