Advancements in the Conversion of Lipid-Rich Biowastes and Lignocellulosic Residues into High-Quality Road and Jet Biofuels Using Nanomaterials as Catalysts

Abstract

At present, the majority of available road and jet biofuels are produced from oleochemical feedstocks that include vegetable oils and biowastes such as waste cooking oils and animal fats. Additionally, one of the most promising ways to achieve long-term environmental goals is to sustainably use lignocellulosic residues. These resources must be treated through a deoxygenation process and subsequent upgrading processes to obtain high-quality road and jet biofuels. Accordingly, in this review, we explore recent advancements in the deoxygenation of oleochemical and lignocellulosic feedstocks in the absence of hydrogen to produce high-quality road and jet biofuels, mainly focusing on the use of nanomaterials as catalysts and the valorization of lipid-rich biowastes and lignocellulosic residues. As a result, we found that regardless of the catalyst particle size, the coexistence of basic sites and weak/medium acid sites is highly important in catalytic systems. Basic sites can enhance the removal of oxygenates via decarboxylation and decarbonylation reactions and inhibit coke formation, while weak/medium acid sites can enhance the cracking reaction. Additionally, the extraction of value-added derivatives from lignocellulosic residues and their subsequent upgrade require the use of advanced methods such as the lignin-first approach and condensation reactions.