Utilization of Spent Sorbent in the Production of Ceramic Bricks

Abstract

The composition and technology for the production of semi-dry ceramic bricks using a nanostructured complex sorbent based on bentonite clay of the 11th horizon of the Tagan deposit of the Republic of Kazakhstan and basalt fiber (gabbro-diabase) of the Karauzek deposit of East Kazakhstan have been developed. The characteristics, chemical composition, and structure of the spent sorbent are given based on electron microscopic and X-ray phase analyses. A number of physical and mechanical parameters have been studied to evaluate the spent sorbent as a raw material for the production of ceramic products. The microstructures of fired ceramic samples with loam and spent sorbent have been studied, and the features of their structure have been revealed. The environmental safety of waste sorbents utilization by extraction in acidic, alkaline, and neutral media with the determination of the content of chromium, zinc, and iron ions has been studied. Experimentally obtained data indicate an insignificant concentration of chromium and zinc ions, not exceeding 3.5 µg/L. Relatively high concentrations of iron ions in ceramic bricks are associated with their high content in the feedstock and in the spent sorbent. It has been established that the introduction of the spent sorbent in the amount of 25% of the total mass increases the strength of the final product from 10.8 to 15.8 MPa, which corresponds to the M125 ceramic brick grade.