The Alkyne Zipper Reaction: A Useful Tool in Synthetic Chemistry

Author:

Sørskår Åshild Moi,Stenstrøm Helge Ø. K.,Stenstrøm YngveORCID,Antonsen Simen GjelsethORCID

Abstract

The alkyne zipper reaction is an internal-to-terminal alkyne isomerization reaction with many interesting applications in synthetic chemistry, as it constitutes an efficient means of achieving acetylene functionalization. A review of its applications in synthesis processes is presented in this paper, with a brief overview of the mechanistic features of the alkyne zipper reaction, as well as a brief overview of its future potential.

Publisher

MDPI AG

Subject

General Medicine

Reference154 articles.

1. Saline hydrides and superbases in organic reactions. IX. Acetylene zipper. Exceptionally facile contrathermodynamic multipositional isomeriazation of alkynes with potassium 3-aminopropylamide;Brown;J. Am. Chem. Soc.,1975

2. Saline hydrides and superbases in organic reactions. VII. Potassium hydride, highly active new hydride reagent. Reactivity, applications, and techniques in organic and organometallic reactions;Brown;J. Org. Chem.,1974

3. The Sodium Amide Catalyzed Rearrangement of Some Acetylenes in Ethylenediamine1a;Wotiz;J. Org. Chem.,1966

4. Chimie Organique—L’emploi du tertibutylate de sodium dans l’alcool tertiobutylique anhydre comme agent disomerisation des hydrocarbures acetyleniques;Smadja;Comptes Rendus Hebd. Des Séances De L’académie Des Sci.,1963

5. Carbanionic isomerization of linear hydrocarbons-acetylenes-allenes-conjugated dienes;Smadja;Ann. Chim.,1965

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3