One-Pot Synthesis of Stable Poly([c2]Daisy–chain Rotaxane) with Pseudo-Stopper via Metathesis Reaction and Thiol-Ene Reaction

Author:

Kamoto Risako1,Onimura Kenjiro1,Yamabuki Kazuhiro1ORCID

Affiliation:

1. Graduate School of Sciences and Technology for Innovation, Yamaguchi University, 2-16-1 Tokiwadai, Ube 755-8611, Yamaguchi, Japan

Abstract

Rotaxanes, known as supramolecular compounds, are expected to find applications in functional materials due to their high degree of freedom. However, their synthesis requires multistep reactions, and there is a demand for more convenient methods to synthesize rotaxane materials. In this study, we aimed to investigate a simpler method for synthesizing highly functional rotaxane materials and explore the diversity of molecular designs. To achieve this, we successfully synthesized a host–guest conjugated compound that incorporates both crown ether as the host unit and secondary ammonium salts as the guest unit within the same molecule. Subsequently, the metathesis reaction of these compounds, which construct [c2]daisy-chain rotaxanes, enabled the one-pot synthesis of a topological polymer called “poly([c2]daisy-chain rotaxane)” with a pseudo-stopper. This methodology achieves the stabilization and polymerization of rotaxanes simultaneously, contributing to the easy materialization of rotaxanes. Furthermore, the thiol-ene reaction achieved the extension of the distance between rotaxane units and provided a useful approach to diversify the design of functional materials with rotaxane structures.

Publisher

MDPI AG

Subject

General Medicine

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