A Short Review of Cavity-Enhanced Raman Spectroscopy for Gas Analysis

Abstract

The market of gas sensors is mainly governed by electrochemical, semiconductor, and non-dispersive infrared absorption (NDIR)-based optical sensors. Despite offering a wide range of detectable gases, unknown gas mixtures can be challenging to these sensor types, as appropriate combinations of sensors need to be chosen beforehand, also reducing cross-talk between them. As an optical alternative, Raman spectroscopy can be used, as, in principle, no prior knowledge is needed, covering nearly all gas compounds. Yet, it has the disadvantage of a low quantum yield through a low scattering cross section for gases. There have been various efforts to circumvent this issue by enhancing the Raman yield through different methods. For gases, in particular, cavity-enhanced Raman spectroscopy shows promising results. Here, cavities can be used to enhance the laser beam power, allowing higher laser beam-analyte interaction lengths, while also providing the opportunity to utilize lower cost equipment. In this work, we review cavity-enhanced Raman spectroscopy, particularly the general research interest into this topic, common setups, and already achieved resolutions.