(1R,3R,5S,Z)-2-Ethylidene-6,6-dimethyl-3-vinylbicyclo[3.1.1]-heptane-Reference-Cited by-同舟云学术

(1R,3R,5S,Z)-2-Ethylidene-6,6-dimethyl-3-vinylbicyclo[3.1.1]-heptane

Published:2024-07-15 Issue:3 Volume:2024 Page:M1850
ISSN:1422-8599
Container-title:Molbank
language:en
Short-container-title:Molbank

Author:

He Zhengjie¹^ORCID,Donaldson William A.¹^ORCID

Affiliation:

1. Department of Chemistry, Marquette University, P. O. Box 1881, Milwaukee, WI 53201-1881, USA

Abstract

(1R,3R,5S,Z)-2-ethylidene-6,6-dimethyl-3-vinylbicyclo[3.1.1]heptane was prepared by hydrovinylation of nopadiene catalyzed by a cationic Ru complex. The structure was fully characterized by 1H- and 13C-NMR spectroscopy, including 2D-COSY and 2D-NOESY spectra, optical rotation, and combustion analysis. In contrast to the previously reported 1,2-hydrovinylation of 1-vinylcycloalkenes by this catalyst, the reaction with nopadiene proceeds by 1,4-addition of ethylene.

Funder

National Institutes of Health

Publisher

MDPI AG

Link

https://www.mdpi.com/1422-8599/2024/3/M1850/pdf

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1. (E)-1-(2,4-Dinitrophenyl)-2-(2-((1R,3R,5S,Z)-2-ethylidene-6,6-dimethylbicyclo[3.1.1]heptan-3-yl)ethylidene)hydrazine;Molbank;2024-07-30