Emerging Developments on Nanocellulose as Liquid Crystals: A Biomimetic Approach

Author:

Thiruganasambanthan Theivasanthi1,Ilyas Rushdan23ORCID,Norrrahim Mohd4ORCID,Kumar Thiagamani56ORCID,Siengchin Suchart67ORCID,Misenan Muhammad8ORCID,Farid Mohammed9,Nurazzi Norizan10ORCID,Asyraf Muhammad11ORCID,Zakaria Sharifah12,Razman Muhammad13ORCID

Affiliation:

1. International Research Center, Kalasalingam Academy of Research and Education, Anand Nagar, Krishnan Koil 626126, India

2. School of Chemical and Energy Engineering, Faculty of Engineering, Universiti Teknologi Malaysia, Johor Bahru 81310, Malaysia

3. Centre for Advanced Composite Materials (CACM), Universiti Teknologi Malaysia, Johor Bahru 81310, Malaysia

4. Research Centre for Chemical Defence, Universiti Pertahanan Nasional Malaysia, Kem Perdana Sungai Besi, Kuala Lumpur 57000, Malaysia

5. Department of Mechanical Engineering, Kalasalingam Academy of Research and Education, Anand Nagar, Krishnan Koil 626126, India

6. Department of Materials and Production Engineering, The Sirindhorn International Thai-German Graduate School of Engineering (TGGS), King Mongkut’s University of Technology North Bangkok, 1518 Wongsawang Road, Bangsue, Bangkok 10800, Thailand

7. Institute of Plant and Wood Chemistry, Technische Universität Dresden, Pienner Str. 19, 01737 Tharandt, Germany

8. Department of Chemistry, College of Arts and Science, Yildiz Technical University, Davutpasa Campus, Istanbul 34220, Turkey

9. Department of Bioprocess Technology, Faculty of Biotechnology and Biomolecular Sciences, Universiti Putra Malaysia, Serdang 43400, Malaysia

10. Center for Defence Foundation Studies, Universiti Pertahanan Nasional Malaysia, Kem Perdana Sungai Besi, Kuala Lumpur 57000, Malaysia

11. Institute of Energy Infrastructure, Universiti Tenaga Nasional, Jalan IKRAM-UNITEN, Kajang 43000, Malaysia

12. Research Centre for Environment, Economic and Social Sustainability (KASES), Institute for Environment and Development (LESTARI), Universiti Kebangsaan Malaysia (UKM), Bangi 43600, Malaysia

13. Research Centre for Sustainability Science and Governance (SGK), Institute for Environment and Development (LESTARI), Universiti Kebangsaan Malaysia (UKM), Bangi 43600, Malaysia

Abstract

Biomimetics is the field of obtaining ideas from nature that can be applied in science, engineering, and medicine. The usefulness of cellulose nanocrystals (CNC) and their excellent characteristics in biomimetic applications are exciting and promising areas of present and future research. CNCs are bio-based nanostructured material that can be isolated from several natural biomasses. The CNCs are one-dimensional with a high aspect ratio. They possess high crystalline order and high chirality when they are allowed to assemble in concentrated dispersions. Recent studies have demonstrated that CNCs possess remarkable optical and chemical properties that can be used to fabricate liquid crystals. Research is present in the early stage to develop CNC-based solvent-free liquid crystals that behave like both crystalline solids and liquids and exhibit the phenomenon of birefringence in anisotropic media. All these characteristics are beneficial for several biomimetic applications. Moreover, the films of CNC show the property of iridescent colors, making it suitable for photonic applications in various devices, such as electro-optical devices and flat panel displays.

Funder

Dana Pecutan Penerbitan

Publisher

MDPI AG

Subject

Polymers and Plastics,General Chemistry

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