Selective Cesium Adsorptive Removal on Using Crosslinked Tea Leaves

Abstract

To remove the radioactive cesium from the polluted environment, tea leaves were chosen as cheap, and abundantly available environment-friendly bio-adsorbents to investigate the alkali metals adsorption. Fresh and used tea leaves (FT and UT) were found to have high efficiency and selectivity for cesium adsorption, after the crosslinking with concentrated sulfuric acid. Calculation of the proton-exchanged amount suggested adsorption mechanism of three alkali metals on crosslinked tea leaves involve a cationic exchange with a proton from the hydroxyl groups of the crosslinked tea leaves, as well as coordination with ethereal oxygen atoms to form the chelation. Further, considering the practical application of the polluted water treatment, the competitive adsorption of Cs+ and Na+ ions was investigated by the batch-wise method and column chromatography separation. Unlike the conventional ion exchange and chelate resins with less selectivity for Cs+ coexisting cations, both crosslinked fresh tea leaves (CFT) and crosslinked used tea leaves (CUT) exhibited Cs selectivity over Na. In addition, batch adsorption studies revealed that the cesium adsorptions were driven by the Langmuir isotherm model; the capacity of both crosslinked tea leaves for cesium adsorption was determined to be around 2.5 mmol g−1. The adsorption capacities are sufficiently higher in comparison with those of synthetic polymers, inorganic ion-exchangers, and other bio-adsorbents.