Specific Alcohol-Responsive Photonic Crystal Sensors Based on Host-Guest Recognition

Author:

Cai Xiaolu1,Zhang Xiaojing2,Fan Jing1,Zheng Wenxiang1,Zhang Tianyi1,Qiu Lili1ORCID,Meng Zihui1

Affiliation:

1. School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China

2. Quality Control Center Department, Sinosteel Luoyang Institute of Refractories Research Co., Ltd., Luoyang 471039, China

Abstract

A photonic crystal material based on β-cyclodextrin (β-CD) with adsorption capacity is reported. The materials ((A-β-CD)-AM PC) consist of 3D poly (methyl methacrylate) (PMMA) colloidal microsphere arrays and hydrogels supplemented with β-cyclodextrin modified by acryloyl chloride. The prepared materials are then utilized for VOCs gas sensing. The 3D O-(A-β-CD)-AM PC was used to detect toluene, xylene, and acetone and the response was seen as the red-shift of the reflection peak. The 3D I-(A-β-CD)-AM PC was used to detect toluene, xylene, and acetone which occurred redshifted, while methanol, ethanol, and propanol and the peaks’ red-shifting was observed. However, among these, methanol gave the largest red-shift response The sensor has broad prospects in the detection of alcohol and the detection of alcohol-loaded drug releases in the future.

Funder

National Natural Science Foundation of China

Publisher

MDPI AG

Subject

Polymers and Plastics,Organic Chemistry,Biomaterials,Bioengineering

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