Cis-Bis(2,2′-Azopyridinido)dicarbonylruthenium(II)-Reference-Cited by-同舟云学术

Cis-Bis(2,2′-Azopyridinido)dicarbonylruthenium(II)

Published:2021-01-18 Issue:1 Volume:2021 Page:M1182
ISSN:1422-8599
Container-title:Molbank
language:en
Short-container-title:Molbank

Author:

Takase Tsugiko,Kainuma Shuya,Kanno Takatoshi,Oyama Dai^ORCID

Abstract

An [Ru(apy)2Cl2] precursor (apy = 2,2′-azopyridine) in 2-methoxyethanol was heated under a pressurized CO atmosphere to afford a diradical complex, [Ru(apy·−)2(CO)2], containing one-electron-reduced azo anion radical ligands. The electronic states of the complex were characterized by spectroscopic techniques and computational studies. Magnetic measurements revealed the existence of antiferromagnetic interactions in the diradical complex.

Funder

Japan Society for the Promotion of Science

Publisher

MDPI AG

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://www.mdpi.com/1422-8599/2021/1/M1182/pdf

Reference22 articles.

1. Complexes with 2,2â²-azobispyridine and related 'S-frame' bridging ligands containing the azo function

2. Chemistry of Metal-Bound Anion Radicals. A Family of Mono- and Bis(azopyridine) Chelates of Bivalent Ruthenium

3. Sensitive Valence Structures of [(pap)2Ru(Q)]n (n = +2, +1, 0, −1, −2) with Two Different Redox Noninnocent Ligands, Q = 3,5-Di-tert-butyl-N-aryl-1,2-benzoquinonemonoimine and pap = 2-Phenylazopyridine

4. Novel [Ru(polypyridine)(CO)2Cl2] and [Ru(polypyridine)2(CO)Cl]+-type complexes: Characterizing the effects of introducing azopyridyl ligands by electrochemical, spectroscopic and crystallographic measurements

5. Redox Induced Electron Transfer in Doublet Azo-Anion Diradical Rhenium(II) Complexes. Characterization of Complete Electron Transfer Series

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