Ex Situ Stabilization/Solidification Approaches of Marine Sediments Using Green Cement Admixtures

Abstract

The routine dredging of waterways produces huge volumes of sediments. Handling contaminated dredged sediments poses significant and diverse challenges around the world. In recent years, novel and sustainable ex situ remediation technologies for contaminated sediments have been developed and applied. This review article focuses on cement-based binders in stabilizing contaminants through the stabilization/solidification (S/S) technique and the utilization of contaminated sediments as a resource. Through S/S techniques, heavy metals can be solidified and stabilized in dense and durable solid matrices, reducing their permeability and restricting their release into the environment. Industrial by-products like red mud (RM), soda residue (SR), pulverized fly ash (PFA), and alkaline granulated blast furnace slag (GGBS) can immobilize heavy metal ions such as lead, zinc, cadmium, copper, and chromium by precipitation. However, in a strong alkali environment, certain heavy metal ions might dissolve again. To address this, immobilization in low pH media can be achieved using materials like GGBS, metakaolin (MK), and incinerated sewage sludge ash (ISSA). Additionally, heavy metals can be also immobilized through the formation of silicate gels and ettringites during pozzolanic reactions by mechanisms such as adsorption, ion exchanges, and encapsulation. It is foreseeable that, in the future, the scientific community will increasingly turn towards multidisciplinary studies on novel materials, also after an evaluation of the effects on long-term heavy metal stabilization.