Degradation of Crystal Violet by Catalytic Wet Peroxide Oxidation (CWPO) with Mixed Mn/Cu Oxides

Abstract

The environment protection has been the starting point for the development of new technologies, which allow the control of highly toxic substances present in the effluents of various industries, whose removal is not feasible by conventional methods. In this research, mixed oxide catalysts Mn and Cu in different molar ratios were prepared from the autocombustion method and characterized by XRD, XRF, TPR-H2, and N2 adsorption–desorption isotherms. The solids were evaluated in the catalytic wet peroxide oxidation of crystal violet (CV) with mild conditions of reaction: 25 °C, normal pressure, airflow of 2 mL/min, and H2O2 0.1 M (2 mL/h). The experimental results indicated degradations of 100% of CV, conversion of the total organic carbon (TOC) of 74%, and elimination of chemical oxygen demand (COD) of 71% in 90 min of reaction. Additionally, the selectivity was monitored by CG-MS, finding that there was almost complete mineralization in a short reaction time, generating intermediate products such as carboxylic acids, alcohols, and amines that do not cause a serious risk to the environment. The Mn–Cu catalyst with molar ratios of 1:2 was the most promising catalyst, displaying a cooperative effect between the two metals, and demonstrating the importance of the redox properties for the elimination of CV dye in wastewater.