Unravelling the Anisotropic Behavior of Nickel—Wires Prepared through External Magnetic Field Assisted Hydrazine Reduction Method

Abstract

Ni wires, prepared through a hydrazine reduction, were exposed to external magnetic fields of different geometrical shape and configuration during the synthesis denoted as Ni-Non-Magnetic, Ni-Double, Ni-Single, Ni-Ring. Their effect on the wire morphology, magnetization and magnetic anisotropy was then investigated via various characterization techniques viz. X-ray diffraction (XRD), high-resolution field emission scanning electron microscopy (HR-FESEM), and vibrating sample magnetometer (VSM). The polycrystalline single phase of the Ni-wires with face centered cubic symmetry was confirmed through the analysis of XRD patterns. Analysis of HR-FESEM images revealed that the Ni-particles were aligned in form of wire-like morphology. The Ni-single sample formed the wires with minimum diameter compared to the parent sample. The magnetization measurements performed at 300 K and 50 K demonstrated the ferromagnetic behavior of all the samples. The room temperature saturation magnetization (MS) and anisotropy constant (K) of the Ni-wires were reduced upon providing the external field during synthesis. However, the low temperature (50 K) magnetization behavior was rather opposing, indicating enhanced values of MS and K. Among all, Ni-ring sample showed maximum anisotropy with a value of 3.84 × 104 erg/cm3 at 50 K. The ambiguous nature of the anisotropic constant and saturation magnetization ascribed partly to the variation in diameters of Ni-wires and to the intermittent spin-spin exchange interactions of unaligned/partially aligned particles during the synthesis. Briefly, in the present study, it was established that the morphology and magnetic anisotropy of the Ni-wires could be tailored through the external magnetic field assisted synthesis method.