Potassium Recovery from Potassium Solution and Seawater Using Different Adsorbents

Abstract

The potassium (K) sorption characteristics with three adsorbents, natural zeolite, ammonium acetate-treated zeolite, and manganese nodule, were studied and compared to see the potential use of manganese nodule as an alternative K adsorbent. In general, the Langmuir isotherm could fit the K sorption in the KCl solutions at different pH conditions better than the Freundlich isotherm. Based on the Langmuir parameters, the maximum K sorption was greater for the zeolite-based adsorbents (i.e., 40–42 mg g−1) than the manganese nodule (i.e., 2.0 mg g−1) at acidic conditions, while the manganese nodule (i.e., 9.7 mg g−1) showed better K sorption at neutral conditions. With the seawater samples, the zeolite-based adsorbents showed higher K recovery (4–14%) than the manganese nodule (0–8.8%). The K sorption on the zeolite-based adsorbents followed the pseudo-second-order kinetics and the K sorption rates were higher for the treated zeolite than the natural zeolite. The repeated sorption tests showed that the natural zeolite could potentially be reused up to three times without any significant loss of K sorption capacity, while the ammonium acetate-treated zeolite lost its K sorption capacity after the single sorption test. Overall, the results show that the manganese nodule may potentially be the alternative to zeolite for K recovery under certain conditions, yet the zeolite-based adsorbents are generally better than the manganese nodule. Thus, more studies to enhance the K recovery using zeolite, including surface modified zeolite, are recommended.