Application of Silsesquioxanes in the Preparation of Polyolefin-Based Materials

Author:

Białek Marzena1ORCID,Czaja Krystyna1

Affiliation:

1. Institute of Chemistry, University of Opole, Oleska 48, 45-052 Opole, Poland

Abstract

This paper is a review of studies on the use of the polyhedral oligomeric silsesquioxanes (POSS) of various structures in the synthesis of polyolefins and the modification of their properties, namely: (1) components of organometallic catalytic systems for the polymerization of olefins, (2) comonomers in the copolymerization with ethylene, and (3) fillers in composites based on polyolefins. In addition, studies on the use of new silicon compounds, i.e., siloxane–silsesquioxane resins, as fillers for composites based on polyolefins are presented. The authors dedicate this paper to Professor Bogdan Marciniec on the occasion of his jubilee.

Publisher

MDPI AG

Subject

General Materials Science

Reference145 articles.

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2. Nwabunma, D., and Kyu, T. (2008). Polyolefin Composites, John Wiley & Sons.

3. Kickelbick, G. (2007). Hybrid Materials. Synthesis, Characterization, and Applications, WILEY-VCH Verlag GmbH & Co. KGaA.

4. Hybrid Materials—Past, Present and Future;Kickelbick;Hybrid Mater.,2014

5. Hartmann-Thompson, C. (2011). Applications of Polyhedral Oligomeric Silsesquioxanes, Springer Science & Business Media.

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