Highly Selective Adsorption of 99TcO4−/ReO4− by a Novel Polyamide-Functionalized Polyacrylamide Polymer Material

Author:

Qin Ben,Hu Yanqin,Xie Meiying,Xue Liyan,Liao Chunfa,Yang FanORCID

Abstract

The treatment of radioactive wastewater is one of the major problems in the current research. With the development of nuclear energy, the efficient removal of 99TcO4− in radioactive wastewater has attracted the attention of countries all over the world. In this study, a novel functional polyamide polymer p-(Amide)-PAM was synthesized by the two-step method. The experimental results show that p-(Amide)-PAM has good adsorptive properties for 99TcO4−/ReO4− and has good selectivity in the nitric acid system. The kinetics of the reaction of p-(Amide)-PAM with 99TcO4−/ReO4− was studied. The results show that p-(Amide)-PAM has a fast adsorption rate for 99TcO4−/ReO4−, the saturated adsorption capacity reaches 346.02 mg/g, and the material has good reusability. This new polyamide-functionalized polyacrylamide polymer material has good application prospects in the removal of 99TcO4− from radioactive wastewater.

Funder

National Key Research and Development Program of China

independent deployment project of Ganjiang Innovation Research Institute of Chinese Academy of Sciences

key deployment project of the Chinese Academy of Sciences

independent deployment project of Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China

Fund of Science and Technology on Reactor Fuel and Materials Laboratory

Publisher

MDPI AG

Subject

Chemical Health and Safety,Health, Toxicology and Mutagenesis,Toxicology

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