Impact of Pressure on Arsenic Released from Pore Water in Clayey Sediment

Abstract

Overpumping can cause arsenic to be released from the pore water in clayey aquitards into aquifers. The amount of water pumped during groundwater exploitation may change over time, leading to different soil-compaction rates or patterns. However, the impact of pressure on the release of arsenic during the compaction of a clayey aquitard is poorly understood. We performed a laboratory-compaction experiment using clayey sediment to identify the effects of compaction rates and patterns on arsenic release by analyzing the chemical characteristics and arsenic species present in pore water samples collected at different stages of the compaction experiment. A rapid (PV increased linearly) and a slow (PV increased exponentially) water-release patterns were recognized according to the compaction rate. We observed that arsenic concentrations in the slow pattern (6.7 to 36.4 μg/L) were considerably higher than those in the rapid pattern (7.6 to 16.1 μg/L). Furthermore, concentrations were the highest in the accelerated compaction pattern (16.8 to 47.4 μg/L), followed by those in the constant and decelerated patterns (4.3 to 14.4 μg/L). Overall, compaction rate and pattern did not alter the arsenic-release mechanism; however, they did alter the moisture content of the sediment at each stage, which indirectly led to differences in the released arsenic concentrations. These results suggest that pumping rates and patterns must be considered to prevent arsenic contamination in groundwater-extraction scenarios.