Low-Permeability Layered Clay Soil Hinders Organic Macromolecular Pollutant Migration in the Transition Zone of the Jianghan Plain–Dabie Mountain Area

Abstract

With the development of industry and agriculture, the level of organic pollutants in groundwater exceeds the standard in some parts of the transition zone of the Jianghan Plain–Dabie Mountain area. To investigate the ability of low-permeability layered clay soil in the study area to hinder the migration of organic macromolecular pollutants, the traditional tracer fluorescein sodium was used to represent organic macromolecular pollutants. The adsorption and migration behavior of organic macromolecular pollutants in the layered soil were explored through indoor experiments. Additionally, a one-dimensional soil column solute transport model was established for the study area using HYDRUS-1D to obtain the dispersivities and dispersion coefficients of organic macromolecular pollutants in layered clay soil. The results showed that the breakthrough duration of sodium fluorescein was up to 116 days in silty clay soil, while the breakthrough duration in sandy sub-sandy soil was only 2.6 days. The dispersion coefficient of organic macromolecular pollutants was only 0.0038 cm2/d in silty clay soil, while the dispersion coefficient was up to 4.724 cm2/d in sandy sub-sandy soil. The dispersion coefficient decreased with the increasing clay fraction of the soil. Compared with homogeneous soil, the dispersivity of organic macromolecular pollutants in clayed soil decreased, and the dispersion coefficient also changed. It indicates that the layered clay soil in the study area effectively hinders the downward migration of organic macromolecular pollutants due to its low permeability and pollutant adsorption capacity. Simultaneously, the lateral transport of water at different soil interfaces in layered soil prolongs the time for organic macromolecular pollutants to reach the underlying aquifer. Low-permeability clay soil may act as a short-term barrier to the migration of organic pollutants to deeper soil and groundwater in the study area. This study provides data support and a theoretical basis for future pollution prevention and control in the Jianghan Plain–Dabie Mountain area.