Sludge Fiber Waste and Kraft Lignin Powder as Fillers in Polylactic Acid Biocomposites: Physical, Mechanical, and Thermal Properties

Abstract

In this investigation, sludge fibre waste (SFW) and Kraft lignin powder (KLP) are introduced into polylactic acid (PLA) matrix biocomposites. These alternative materials allow for both the reuse of fibre waste from paper mill sludge and a reduction in the amount of high-cost biopolymer used in the same volume. Proportions from 10 to 40 wt.% of SFW with the addition of 2.5% and 5% of KLP are incorporated in PLA by extrusion and injection moulding. The thermogravimetric properties, water absorption, tensile and flexural properties, and morphology of the fabricated biocomposites were investigated. According to the results, KLP contributes to thermically stabilising the loss resulting from the incorporation of SFW. Flexural and tensile tests reveal a more pronounced decrease in strength with an SFW ratio above 10%. The modulus of elasticity increases significantly with an SFW ratio above 20%. The strength properties are stabilised with the addition of 5% KLP. The addition of KLP presents a tendency to reduce water absorption obtained by the incorporation of SFW into biocomposites. Scanning electron micrographs evidence that KLP improves the interfacial adhesion by reducing the voids between fibres and PLA.