The Influence of Groundwater Migration on Organic Matter Degradation and Biological Gas Production in the Central Depression of Qaidam Basin, China

Abstract

For insight into the productive and storage mechanisms of biogas in the Qaidam Basin, efforts were made to investigate the groundwater recharge and the processes of hydrocarbon generation by CDOM-EEM (fluorescence excitation-emission matrix of Chromophoric dissolved organic matter) spectrum, hydrogen and oxygen isotopes, and geochemical characters in the central depression of the Qaidam Basin, China. The samples contain formation water from three gas fields (TN, SB, and YH) and surrounding surface water (fresh river and brine lake). The results indicate that modern precipitation significantly controls the salinity distribution and organic matter leaching in the groundwater system of the central depression of the Qaidam Basin. Higher salinity levels inhibit microbial activity, which leads to organic matter degradation and to gas generation efficiency being limited in the groundwater. The inhabitation effect is demonstrated by the notable negative correlation between the extent of organic matter degradation and its concentration with hydrogen and oxygen isotopes. The conclusion of this study indicated that modern precipitation emerges as a crucial factor affecting the biogas production and storage in the Qaidam Basin by influencing the ultimate salinity and organic matter concentration in the formation, which provides theoretical insight for the maintenance of modern gas production wells and the assessment of gas production potential.