2,2′-Trisulfanediyldibenzoyl Chloride-Reference-Cited by-同舟云学术

2,2′-Trisulfanediyldibenzoyl Chloride

Published:2023-09-21 Issue:3 Volume:2023 Page:M1731
ISSN:1422-8599
Container-title:Molbank
language:en
Short-container-title:Molbank

Author:

Aitken R. Alan¹^ORCID,Campbell Alexandra H.¹,Fletcher Chloé E.¹,Slawin Alexandra M. Z.¹^ORCID

Affiliation:

1. EaStCHEM School of Chemistry, University of St Andrews, North Haugh, St Andrews, Fife KY16 9ST, UK

Abstract

The X-ray structure of the title compound, formed at low conversion in the reaction of thiosalicylic acid with thionyl chloride, has been determined. The acid chloride groups are oriented to permit an attractive non-bonding O…S interaction. Mechanisms are suggested for the formation of this unexpected product. 1H and 13C NMR data are also reported for the first time for the major reaction product, 2-mercaptobenzoyl chloride.

Publisher

MDPI AG

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

https://www.mdpi.com/1422-8599/2023/3/M1731/pdf

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