Abstract
A new heterohexanuclear ZnII–EuIII dimer [{(ZnL)2Eu}2(bdc)2]·2Cl constructed from a N2O2-type chelating ligand H2L (6,6′-Dimethoxy-2,2′-[ethylenedioxybis(nitrilomethylidyne)]diphenol), Zn(OAc)2·2H2O, EuCl3·6H2O and H2bdc (terephthalic acid) was synthesized, and characterized using elemental analyses, IR (Infrared), UV-Vis (Ultraviolet–visible) spectra and X-ray single crystal diffraction method. There are two crystallographically equivalent [(ZnL)2Eu] moieties in the ZnII–EuIII complex, the two [(ZnL)2Eu] moieties are linked by two bdc2– ligand leading to a heterohexanuclear dimer, in which the carboxylato groups bridge the ZnII and EuIII atoms. Furthermore, the luminescence properties of H2L and its ZnII–EuIII complex have been studied.
Funder
the National Natural Science Foundation of China
Program for Excellent Team of Scientific Research in Lanzhou Jiaotong University
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering
Cited by
7 articles.
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