OLED Structure Optimization for Pure and Efficient NIR Electroluminescence of Nd3+ Complexes Bearing Fluorinated 1,3-Diketones

Author:

Metlina Daria A.1,Goryachii Dmitry O.1,Metlin Mikhail T.1ORCID,Mikhalchenko Lyudmila V.2,Korshunov Vladislav M.1,Taydakov Ilya V.13ORCID

Affiliation:

1. P.N. Lebedev Physical Institute of the Russian Academy of Sciences, 53 Leninsky Prospect, 119991 Moscow, Russia

2. N.D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, 47 Leninsky Prospect, 119991 Moscow, Russia

3. G.V. Plekhanov Russian University of Economics, 36 Stremyanny per., 117997 Moscow, Russia

Abstract

NIR emitting OLEDs (organic light-emitting diodes) with high photoluminescence quantum yields were developed on the basis of fluorinated 1,3-diketonate coordination compounds of the Nd3+ ion. Both thermal evaporation and spin-coating techniques were successfully employed for active layer deposition resulting in electroluminescence quantum yields up to 1.38·10−2%. Blueish-green emission from exciplex and electroplax formations was almost suppressed with the topology optimization of the cell.

Funder

Russian Science Foundation

Publisher

MDPI AG

Subject

General Materials Science

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