Affiliation:
1. Department of Chemical Engineering, Toronto Metropolitan University, Toronto, ON M5B 2K3, Canada
Abstract
Fabrication, characterization and testing of protective biomimetic orthopedic footwear advanced insole materials are introduced. The main objective of this material is to preserve and isolate a set of sensors for the Weight-Bearing Monitoring System (WBMS) device. Twenty-one samples of renewably sourced Polyurethane Foam (PUF) composed of poly(trimethylene ether) glycol (PO3G) and unmodified castor oil (CO) were synthesized and evaluated according to predetermined criteria. Response surface methodology of Box—Behnken design was applied to study the effect of the polyols ratio, isocyanate index (II), and blowing agent ratio on the properties (hardness, density) of PUFs. Results showed that CO/PO3G/Tolyene Diisocyanate (TDI) PUFs with hardness Shore A 17–22 and density of 0.19–0.25 g/cm3 demonstrate the required characteristics and can potentially be used as a durable and functional insole material. Phase separation studies have found the presence of well-segregated structures in PUFs having polyols ratio of CO:PO3G 1:3 and low II, which further explains their extraordinary elastic properties (400% elongation). Analysis of cushioning performance of PUF signified that five samples have Cushioning Energy (CE) higher than 70 N·mm and Cushioning Factor (CF) in the range of 4–8, hence are recommended for application in WBMS due to superior weight-bearing and pressure-distributing properties. Moreover, the developed formulation undergoes anaerobic soil bacterial degradation and can be categorized as a “green” bio-based material.
Funder
Ontario Centres of Excellence
Subject
Molecular Medicine,Biomedical Engineering,Biochemistry,Biomaterials,Bioengineering,Biotechnology
Reference26 articles.
1. North, K., Maass, S.D., and Hitchcock, R.W. (September, January 31). An Insole Sensor for Recording Weight Bearing Behavior during Tibial Fracture Rehabilitation. Proceedings of the 2010 Annual International Conference of the IEEE Engineering in Medicine and Biology Society, EMBC’10, Buenos Aires, Argentina.
2. Sensitronics (2023, March 28). FSR 101 Force Sensing Resistor Theory and Applications. Available online: https://www.sensitronics.com/pdf/Sensitronics_FSR_101.pdf.
3. Effects of temperature on the material characteristics of midsole and insole footwear foams subject to quasi-static compressive and shear force loading;Shariatmadari;Mater. Des.,2012
4. Compressive behavior after simulated service conditions of some foamed materials intended as orthotic shoe insoles;Campbell;J. Rehabil. Res. Dev.,1984
5. A comparison of shoe insole materials in plantar pressure relief;Leber;Prosthet. Orthot. Int.,1986