Reasoning and Logical Proofs of the Fundamental Laws: “No Hope” for the Challengers of the Second Law of Thermodynamics

Author:

Kostic Milivoje1ORCID

Affiliation:

1. Department of Mechanical Engineering, Northern Illinois University, DeKalb, IL 60115, USA

Abstract

This comprehensive treatise is written for the special occasion of the author’s 70th birthday. It presents his lifelong endeavors and reflections with original reasoning and re-interpretations of the most critical and sometimes misleading issues in thermodynamics—since now, we have the advantage to look at the historical developments more comprehensively and objectively than the pioneers. Starting from Carnot (grand-father of thermodynamics to become) to Kelvin and Clausius (fathers of thermodynamics), and other followers, the most relevant issues are critically examined and put in historical and contemporary perspective. From the original reasoning of generalized “energy forcing and displacement” to the logical proofs of several fundamental laws, to the ubiquity of thermal motion and heat, and the indestructibility of entropy, including the new concept of “thermal roughness” and “inevitability of dissipative irreversibility,” to dissecting “Carnot true reversible-equivalency” and the critical concept of “thermal-transformer,” limited by the newly generalized “Carnot-Clausius heat-work reversible-equivalency (CCHWRE),” regarding the inter-complementarity of heat and work, and to demonstrating “No Hope” for the “Challengers” of the Second Law of thermodynamics, among others, are offered. It is hoped that the novel contributions presented here will enlighten better comprehension and resolve some of the fundamental issues, as well as promote collaboration and future progress.

Publisher

MDPI AG

Subject

General Physics and Astronomy

Reference25 articles.

1. This comprehensive treatise is written for the special occasion of the author’s 70th birthday. It presents his lifelong endeavors and reflections with original reasoning and re-interpretations of the most critical and misleading issues in thermodynamics. Only selected and this author’s relevant publications are referenced, since the goal was not to review the vast thermodynamic literature.

2. (2023, July 05). Entropy Special Issue, “Exploring Fundamentals and Challenges of Heat, Entropy, and the Second Law of Thermodynamics: Honoring Professor Milivoje M. Kostic on the Occasion of His 70th Birthday”. Available online: https://www.mdpi.com/journal/entropy/special_issues/70th.

3. Thurston, R.H. (1897). Reflections on the Motive Power of Heat, Chapman & Hall, Ltd.. Available online: https://sites.google.com/site/professorkostic/energy-environment/sadi-carnot.

4. Thomson, W. (2023, July 05). On the Dynamical Theory of Heat. Transactions of the Royal Society of Edinburgh, March 1851, and Philosophical Magazine IV. Available online: https://zapatopi.net/kelvin/papers/.

5. Clausius, R. (1879). The Mechanical Theory of Heat, Macmillan.

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