Characterization and Source Analysis of Pollution Caused by Atmospheric Volatile Organic Compounds in the Spring, Kunming, China

Abstract

The surface atmospheric O3 concentration in Kunming shows a significant upward trend, with high values mainly occurring in March–May. Volatile organic compounds (VOCs) are one of the most important precursors of O3. However, the sources of VOCs are complex and difficult to identify. In order to understand the pollution levels, the spatial distribution characteristics, and possible sources of VOCs, we conducted simultaneous offline sampling at representative sites in six different functional areas of Kunming using SUMMA canisters for one week. The VOC samples were analyzed via GC/MS. The VOC data were analyzed (using the feature ratio method, ozone formation potential (OFP), and Positive Matrix Factorization (PMF) model). Some important conclusions were drawn. Firstly, VOCs during the spring in Kunming were mainly derived from oxygenated VOCs, aromatic hydrocarbons, and halogenated hydrocarbons, with significant spatial differences. Secondly, we found that the potential for atmospheric ozone formation is higher in Kunming for aromatic hydrocarbons and oxygenated VOCs. Finally, the results of the Positive Matrix Factorization model (PMF) showed that Kunming’s ambient atmospheric VOCs mainly originate from anthropogenic source emissions. These conclusions can provide useful reference information for O3 pollution control in Kunming.