Effect of Red Mud Addition on Electrical and Magnetic Properties of Hemp-Derived-Biochar-Containing Epoxy Composites

Author:

Zecchi Silvia1ORCID,Ruscillo Fabrizio1,Cristoforo Giovanni1,Bartoli Mattia23,Loebsack Griffin4,Kang Kang4,Piatti Erik1ORCID,Torsello Daniele15ORCID,Ghigo Gianluca15ORCID,Gerbaldo Roberto15ORCID,Giorcelli Mauro13ORCID,Berruti Franco4,Tagliaferro Alberto13ORCID

Affiliation:

1. Department of Applied Science and Technology, Politecnico di Torino, C.so Duca degli Abruzzi 24, 10129 Torino, Italy

2. Center for Sustainable Future Technologies, Italian Institute of Technology, Via Livorno 60, 10144 Torino, Italy

3. Consorzio Interuniversitario Nazionale per la Scienza e Tecnologia dei Materiali (INSTM), Via G. Giusti 9, 50121 Firenze, Italy

4. Department of Chemical and Biochemical Engineering, Institute for Chemicals and Fuels from Alternative Resources (ICFAR), Western University, London, ON N6A 5B9, UK

5. Istituto Nazionale di Fisica Nucleare, Sez. Torino, Via P. Giuria 1, 10125 Torino, Italy

Abstract

Waste stream valorization is a difficult task where the economic and environmental issues must be balanced. The use of complex metal-rich waste such as red mud is challenging due to the wide variety of metal oxides present such as iron, aluminum, and titanium. The simple separation of each metal is not economically feasible, so alternative routes must be implemented. In this study, we investigated the use of red mud mixed with hemp waste to produce biochar with high conductivity and good magnetic properties induced by the reduction of the metal oxides present in the red mud through carbothermal processes occurring during the co-pyrolysis. The resulting biochar enriched with thermally-reduced red mud is used for the preparation of epoxy-based composites that are tested for electric and magnetic properties. The electric properties are investigated under DC (direct current) regime with or without pressure applied and under AC (alternating current) in a frequency range from 0.5 up to 16 GHz. The magnetic measurements show the effective tailoring of hemp-derived biochar with magnetic structures during the co-pyrolytic process.

Funder

Natural Sciences and Engineering Research Council of Canada

Publisher

MDPI AG

Subject

Electrical and Electronic Engineering,Mechanical Engineering,Control and Systems Engineering

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