Chromium Luminescence in Plasma Electrolytic Oxidation Coatings on Aluminum Surface

Abstract

With plasma electrolytic oxidation (PEO), one can easily obtain thick (tens of microns), mechanically resilient and chemically stable oxide coating on aluminum and other valve metal alloys. The study of luminescent PEO coatings is a relatively new subfield of the already well-established coating preparation methods. In recent years, many new luminescence-based approaches have been developed, one of which is the detection of ionizing radiation of carbon-doped PEO alumina coating. This study presents an improved approach by doping the alumina coating with chromium using citric acid as an additive in the electrolyte. Trivalent chromium ions replacing aluminum in the crystalline lattice of the coating exhibit characteristic sharp lines in the luminescence spectrum. The effectiveness of different DC voltages, process times and citric acid concentrations in electrolyte were examined. The use of citric acid in the electrolyte also provides the conditions required for the formation of an energy trap in the bandgap of the material, thus opening up the possibility for the coating to be used as an ionizing radiation detector by measuring its thermoluminescence. Chromium atoms are incorporated in the coating from the Al6082 aluminum alloy itself and are not added in the electrolyte, therefore making the process much more reliable, repeatable, and environmentally friendly.