Study of Asphalt Behavior on Pre-Wet Aggregate Surface Based on Molecular Dynamics Simulation and Surface Energy Theory

Abstract

The improvement of the performance of asphalt mixtures has been studied by scholars. This research proposes a new asphalt–mineral interface formation method, which is a pre-wet bitumen–mineral mixture. The formation process of the pre-wet asphalt–mineral interface was simulated by molecular dynamics simulation software. The diffusion coefficient, concentration distribution, and interfacial energy of the asphalt on the surface of the pre-wet mineral material and non-pre-wet mineral material were compared and analyzed. The simulation results show that the mineral surface diffusion rate of the asphalt after pre-wetting is increased by more than 50%, and the concentration in the X, Y, and Z directions is reduced by 0.8%, 4.6%, and 7.8%, respectively. At the same time, the interface energy between the bitumen and the pre-wet mineral was increased by more than 8%. The results of the molecular dynamics model are verified based on the surface energy theory and contact angle test. The experimental results show that the contact angle of the asphalt is smaller and the diffusion performance is better after pre-wetting. At the same time, the interface adhesion work between the asphalt and wet mineral surface increased by 4.3% in a dry environment, and the peeling work decreased by 41.1% in a water environment. Therefore, the author believes that the pre-wetting technology of the asphalt mixture has a certain feasibility and practicability.