Chemical Degradation and Color Changes of Paint Protective Coatings Used in Solar Glass Mirrors

Abstract

This paper reports a study of the influence of outdoor natural aging on paint coatings applied to the back of three commercial solar glass mirrors (A1, C2, and D2) under two different exposure environments (marine and desert) in Morocco for a period of about three years. The aging assessment was carried out through colorimetric measurements and FTIR-ATR (Attenuated total reflection-Fourier transform infrared) analyses of the top coat paints. The obtained results demonstrate that the tested coating system had a high resistance at the desert site. Under the desert environment, no obvious changes to the coating occurred after 350 days. However, at the marine site, some color changes were detected, and the coating got yellow and more matte, especially for mirror A1. FTIR-ATR analyses have indicated many modifications in the intensity of many bonds of infrared spectra especially for paint of this mirror type (A1). This chemical degradation is not only due to UV degradation but also related to many factors, such as humidity, salinity, and rainfall. This finding was concluded after the faster degradation observed on samples exposed at the marine site. The present study confirms the need to use different exposure environments for testing the limits of new protective systems for solar glass mirrors rather than using only the real service conditions. Finally, accelerated tests are necessary for understanding the effect of each degrading parameter and their results should be compared to outdoor tests data for a complete analysis of coatings durability.