Achieving Ultralow-Density, High-Purity Au Foam Hohlraum with Hierarchical Porous Structure

Abstract

High Z (atomic number) metallic foams with a low density and high purity are urgent demands in high energy-density physical experiments. They suppress plasma expansion and convert the laser pulses to X-rays more uniformly and efficiently. Thus, we synthesized an ultralow-density and high-purity Au foam hohlraum with a hierarchical porous structure via a template-dealloying method in this paper. Silica (SiO2) beads were introduced as the sacrificial templates due to their high stability at an elevated temperature. The Au and Ag nanoparticles were successively deposited onto the SiO2 templates via an electroless deposition process to form an Ag@Au@SiO2 core-shell structure. Cylindrical Ag@Au@SiO2 hohlraum was achieved using a filter-casting technique with a patented mold. Afterward, an Au-Ag alloy was generated during 36 h of calcination at 400 °C. Self-supported Au foam hohlraum with the hierarchical porous structure was gained after the SiO2 templates were removed, followed by the dealloying of the Ag from the Au-Ag alloy. A self-supporting Au foam hohlraum with a density as low as 0.2 g/cm3 and a purity of 99.37% was achieved, and the density decreased by about 44.5% when compared with our previous Au foam (density: 0.36 g/cm3, purity: less than 96%) using microspherical polystyrene as the sacrificial template. Thus, the ultralow-density, high-purity Au foam hohlraum may exhibit profound application in high-energy physical experiments in the near future.