Durable and Superhydrophobic Aluminium Alloy with Microscale Hierarchical Structures and Anti-Drag Function Inspired by Diving Bell Spider

Abstract

Coating materials with special surface wettability are widely applied in marine paint systems used in the naval industry to reduce the corrosion and viscous drag of seawater. However, traditional coatings are inefficient and limited, either by poor durability or insufficient anti-drag capacity. Here, inspired by the diving bell spider, a bionic superhydrophobic coating with multiscale hierarchical architecture was successfully prepared on the surface of aluminium alloy. It possesses excellent mechanical abrasion durability, chemical durability, and low adhesion. Remarkably, the water contact angles could remain over 150.9° after more than 15 abrasion cycles or strong acid/alkali conditions. In addition, the impacting water droplet lifted off the surface of bionic superhydrophobic aluminium alloy (BSAA) within 13 ms, illustrating an excellent low adhesion property. In fact, when the BSAA is immersed in water, it could absorb bubbles and form a gas membrane. The existence of the gas membrane could prevent water and anaerobic organisms from contacting and even corroding the BSAA. Meanwhile, the gas membrane acts as a lubricant and significantly deceases friction at the solid–liquid interface, reducing the drag for BSAA. The BSAA proposed in this work has broad application prospects, such as medical devices, microfluidic chips, gas separation and collection in water.