Affiliation:
1. College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai 201620, China
Abstract
To enhance protection against corrosion and ice on iron metal material in frigid zones, an organic silicone resin coating was prepared using four monomers. Its structure and performance was analyzed via infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), gel permeation chromatography (GPC), and thermal analysis (TG). Corrosion resistance of coating was tested by saltwater resistance and salt spray resistance and assessed using an electrochemical workstation, alongside anti-icing tests. The results showed that the organic silicone resin was successfully synthesized. The coatings could delay freezing onset by one-third compared to controls in low temperatures, with a detachment time also reduced by one-third, indicating excellent corrosion and ice resistance. The methylphenyl silicone resin had good anti-corrosion and anti-ice properties, with a low corrosion current density (icorr) of 0.8793 μA/cm2 and a high charge transfer resistance (Rct) of 24,930 Ω·cm2 in saline.
Funder
the Special Projects of the Ministry of Science and Technology