The Influence of the Magnetic Field on Ni Thin Film Preparation by Electrodeposition Method and Its Electrocatalytic Activity towards Hydrogen Evolution Reaction

Abstract

Ni thin films were synthesized through the electrodeposition method from three different electrolytes (acetate, borate, and citrate). Furthermore, they were assessed as electrocatalysts for hydrogen evolution reaction (HER) in 1 M NaOH. Herein, various electrodeposition parameters, such as the pH of the electrolytes, the deposition potential, and the influence of the magnetic field, were measured. We compared the different morphologies and characteristics depending on the thin film electrodeposition process parameters. Moreover, we studied the material’s wettability changes based on the electrolyte’s composition and the applied external magnetic field. It was found that the deposited Ni thin film from the citrate electrolyte under the influence of the magnetic field in the perpendicular direction to the electrode surface had the best catalytic performance to HER. It possessed an overpotential value of 231 mV and a Tafel slope of 118 mV dec−1. The deposition process was accomplished by using the chronoamperometry technique. Measuring scanning electron microscope and X-ray diffraction were used to characterize the fabricated films’ surface morphologies and crystalline structures.