The Effect of Self-Healing Microcapsules in Corrosion Testing on Magnesium AZ31 Alloy and Fibre Metal Laminates

Author:

Ostapiuk Monika1ORCID,Bieniaś Jarosław1,Loureiro Mónica V.2ORCID,Marques Ana C.2ORCID

Affiliation:

1. Department of Materials Engineering, Faculty of Mechanical Engineering, Lublin University of Technology, Nadbystrzycka 36, 20-618 Lublin, Poland

2. Centro de Recursos Naturais e Ambiente (CERENA), Departamento de Engenharia Química (DEQ), Instituto Superior Técnico, Universidade de Lisboa, Av. Rovisco Pais 1, 1049-001 Lisboa, Portugal

Abstract

Fibre metal laminates (FMLs) are the most interesting composite materials of the past decade. They possess the properties of both polymer composites and metallic alloys. However, there is a problem with corrosion when the outer layers are made of aluminium or magnesium. The electrochemical changes that occur during the corrosion process and the mechanisms associated with the corrosion phenomenon are still being investigated. Recently, self-healing phenomena have emerged as a useful approach to prevent corrosion. However, there is limited research on the combination of FMLs and self-healing layers. Therefore, the main purpose of this article is to evaluate the self-healing ability of a magnesium/PEO layer based on microcapsules in a corrosion environment. It was observed that the corrosion mechanism in magnesium alloys is very complex. However, the use of a barrier layer with PEO treatment and microcapsules yielded positive anti-corrosion results. The FML samples were subjected to a 6-week corrosion test, and the addition of microcapsules to the layers showed positive results. In contrast, the samples without microcapsules exhibited intergranular corrosion. In the future, comprehensive tests using self-healing microcapsules in FMLs could greatly enhance their anti-corrosion properties and improve the integrity of the structure.

Funder

NAWA

CERENA

Publisher

MDPI AG

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