A Study on Improving the Sensitivity of Indirect X-ray Detectors by Adding Hybrid Perovskite Quantum Dots

Abstract

In this paper, we demonstrate the enhancement in detection sensitivity of an indirect X-ray detector based on poly(3-hexylthiophene) (P3HT) and fullerene derivatives [6,6]-phenyl-C71-butyric acid methyl ester (PC71BM) by adding perovskite quantum dots (PeQDs). The weight ratio of P3HT and PC71BM was fixed at 1:1 (20 mg/mL in chlorobenzene), and different amounts of FAPbBr3 PeQDs of (0–3) mg were added to the P3HT:PC71BM active layer solution. The experimental results show that the detector using P3HT:PC71BM:FAPbBr3 PeQDs (1 mg) achieved a sensitivity of 2.10 mA/Gy∙cm2. To further improve the sensitivity, a ligand exchange experiment was performed on the P3HT:PC71BM:FAPbBr3 PeQDs (1 mg) detector. Under the condition of 12 h ligand exchange time, the detector with P3HT:PC71BM:FAPbBr3 PeQDs (1 mg) showed the highest sensitivity of 2.26 mA/Gy∙cm2, which was increased by 28% compared to the pristine detector with a P3HT:PC71BM active layer.