Structural and Magnetic Specificities of Fe-B Thin Films Obtained by Thermionic Vacuum Arc and Magnetron Sputtering

Abstract

Fe-B based compounds are of high interest due to their special properties and the wide range of involved applications. While B is the element that facilitates the increase in the hardness and the degree of wear resistance, it is also an effective glass former, controlling the formation of a much-desired amorphous structure with specific magnetic properties. Major difficulties related to the proper engineering of Fe-B thin films lay especially in their preparation under well-defined compositions, which in turn, should be accurately determined. The present study closely analyzes the morpho-structural and magnetic properties of thin coatings of Fe-B of approximately 100 nm thickness and with the nominal B content ranging from 5 at. % to 50 at. %. The comparison between films obtained by two preparation methods, namely, the thermionic vacuum arc and the magnetron sputtering is envisaged. Morpho-structural properties were highlighted using X-ray diffraction supplemented with X-ray reflectometry and scanning electron microscopy, whereas the elemental investigations were performed by X-ray dispersive spectroscopy and Rutherford back-scattering spectroscopy. The magnetic properties of the Fe-B layers were carefully investigated by the vectorial magneto-optic Kerr effect and conversion electron Mössbauer spectroscopy. The high capability of Mössbauer Spectroscopy to provide the phase composition and the B content in the formed Fe-B intermetallic films was proven, in correlation to Rutherford back-scattering techniques, and to explain their magnetic properties, including the magnetic texture of interest in many applications, in correlation with longitudinal magneto-optic-Kerr-effect-based techniques.