Analysis of the Physical-Mechanical Properties of the Zinc Phosphate Layer Deposited on a Nodular Cast Iron Substrate

Abstract

The rotors of submersible wastewater pumps, generally made of nodular graphite cast iron, are subjected to complex processes of corrosive erosion during operation. To improve the characteristics of erosion resistance by impact with solid particles in the corrosive environment of wastewater, cast iron was subjected to a chemical phosphating treatment. In the paper, the scratch test behaviour of nodular cast iron and phosphate nodular cast iron is analysed comparatively, studying the behaviour of the deposited layer and its adhesion to the substrate. The nanoindentation characteristics of nodular cast iron and phosphate nodular cast iron were also studied. It was observed that the deposited layer is not compact, but when pressed, it does not crack and does not detach from the substrate; it is impregnated in the substrate in the metal matrix, but not on the area with carbon nodules. The SEM micrographs show that the deposited phosphate layer is relatively porous and can change the behaviour of the liquid flow moving on the surface of the rotor due to its hydrophilic behaviour; this also allows the formation of a boundary layer that adheres to the surface of the rotor and protects it from the impacts of microparticles driven by the liquid stream.