Performance Characterisation and Microscopic Characteristics of Rapeseed Heavy Oil–Diatomaceous Earth Composite-Modified Asphalt

Abstract

In order to further improve the performance of bio-asphalt, because of its poor high-temperature performance, another biomass material, diatomaceous earth, was employed as a composite modifier, and a composite-modified asphalt was made to increase the high-temperature performance of bio-asphalt. The optimal preparation parameters of a rapeseed heavy oil–diatomaceous earth composite-modified asphalt were identified by employing an orthogonal test design. Based on the laboratory test, the physical properties, rheological properties, and microscopic properties of the asphalt were evaluated correspondingly by utilising matrix asphalt, rapeseed heavy oil-modified asphalt, and diatomaceous earth-modified asphalt as the control group. The results of the orthogonal test analysis showed that the optimum preparation parameters of the rapeseed heavy oil–diatomaceous earth composite-modified asphalt were 8% rapeseed heavy oil, 5% diatomaceous earth, a shear period of 35 min, and a shear rate of 2500 r/min. The addition of rapeseed heavy oil improved the fatigue resistance and low-temperature performance of the asphalt, but, at the same time, the asphalt penetration increased, the softening point and viscosity decreased, and the high-temperature rutting resistance decreased. Compared with the matrix asphalt, the viscosity of the rapeseed heavy oil–diatomaceous earth composite-modified asphalt at 135 °C rose by 23.2%. The rutting factor G*/sinδ increased by 45.5%, 15.6%, 17.6%, 29.8%, and 22.0%, while the fatigue factor G*·sinδ increased by 41.9%, 14.2%, 16.7%, 19.4%, and 23.1%, respectively, in the high-temperature rheological properties test temperature interval from 52 °C to 76 °C. The creep stiffness S fell by 16.2%, 36.1%, and 25.2%, while the creep rate m rose by 25.8%, 52.9%, and 13.4%, respectively, in the low-temperature rheological performance test temperature interval from −24 °C to −12 °C. Therefore, diatomaceous earth may effectively counteract the softening effect of the rapeseed heavy oil on the matrix asphalt and may raise the strength level and permanent deformation resistance of the composite-modified asphalt with only partial loss of fatigue resistance. The matrix asphalt, rapeseed oil, and diatomaceous earth exhibited high compatibility. The integration of rapeseed oil and diatomaceous earth largely did not modify the chemical properties of asphalt, and it was able to maintain the qualities of asphalt itself. Rapeseed heavy oil and diatomaceous earth on the thermal stability of the matrix asphalt has the opposite effect. The reorganisation component of diatomaceous earth on the colloidal structure of asphalt is conducive to the stabilisation of the nature of the asphalt, which can significantly improve the temperature stability of asphalt.