Durable and High-Temperature-Resistant Superhydrophobic Diatomite Coatings for Cooling Applications

Author:

Pereira José1ORCID,Souza Reinaldo1,Moreira António1ORCID,Moita Ana2ORCID

Affiliation:

1. IN+ Center for Innovation, Technology and Policy Research, Instituto Superior Técnico, Universidade de Lisboa, Avenida Rovisco Pais, 1049-001 Lisboa, Portugal

2. CINAMIL—Military Academy Research Center, Department of Exact Sciences and Engineering, Portuguese Military Academy, 2720-113 Amadora, Portugal

Abstract

The present work is aimed at the development of superhydrophobic coatings and surfaces with enhanced robustness and boiling temperature resistance. We will address the synthesis method of the coatings, which was based on the preparation of a composite of silanized diatomite particles embedded in epoxy resin. After the synthesis of the composite solution, it was applied by dip-coating in stainless steel substrates and submitted to a post-treatment cure in an oven. The method proved to be a comparatively fast and simple one. Then, the substrate/coating sets were characterized using different techniques, including Fourier transform infrared spectroscopy and scanning electron microscopy, and their water contact angle and roughness were measured. Apart from this, the physical and chemical robustness of the sets was also tested using diverse resistance tests like adhesion strength, abrasion resistance, resistance to strong acids and bases, and resistance to boiling water. The main results are that we obtained robust coatings, with wettability defined by water contact angles above 150°. Also, the synthesized coatings revealed good resistance to boiling water, as their properties were almost unchanged after the completion of a long period of tests. The characterization of the produced coatings suggested their propensity to be explored for use in water boiling surfaces and interfaces for cooling purposes in boiling heat transfer systems.

Funder

Fundação para a Ciência e a Tecnologia

Associação do Instituto Superior Técnico para a Investigação e o Desenvolvimento

Fundação para a Ciência e Tecnologia

Publisher

MDPI AG

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